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Synthesis of β-Truxinate via [2+2] Cycloaddition of Methyl 4-Nitrocinnamate: Kinetic Study of its Isomerization with DBU.
| dc.rights.license | http://creativecommons.org/licenses/by/4.0 - Atribución | es_MX |
| dc.contributor.author | ROBERTO FLORES VELAZQUEZ | es_MX |
| dc.contributor.author | BLANCA EDA DOMINGUEZ MENDOZA | es_MX |
| dc.contributor.author | LUIS GABRIEL HERNANDEZ VAZQUEZ | es_MX |
| dc.contributor.author | Jaime Escalante García | es_MX |
| dc.coverage.spatial | MEX - México | es_MX |
| dc.date | 2024 | |
| dc.date.accessioned | 2024-06-11T21:04:46Z | |
| dc.date.available | 2024-06-11T21:04:46Z | |
| dc.identifier.issn | Digital: 2365-6549, Impreso:2365-6549 | |
| dc.identifier.uri | http://riaa.uaem.mx/handle/20.500.12055/4675 | |
| dc.description | This work concerns the isomerization of the product obtained by dimerization of methyl 4-nitrocinnamate. Subsequent isomerization was performed using 1,8 diazabicyclo [5.4.0] undec-7-ene (DBU) as a base to obtain the corresponding ζ- and δ-truxinate derivatives. The process was monitored by 1HNMR spectroscopy in different deuterated solvents with a wide range of dielectric constants, acetonitrile-d3, acetone-d6, tetrahydrofuran-d8, and benzene-d6. Each solvent was found to have a distinct influence on the reaction’s rate constant k, with acetone-d6 yielding the highest ratio of ζ-truxinate derivative. Kinetic analysis of the reaction provided valuable information about the mechanism involved in the isomerization process. | es_MX |
| dc.format | pdf - Adobe PDF | es_MX |
| dc.language | eng - Inglés | es_MX |
| dc.publisher | Chemistry Europe | es_MX |
| dc.relation.ispartof | Chemestry Select | es_MX |
| dc.relation.ispartofseries | 22 | es_MX |
| dc.relation.haspart | 8 | es_MX |
| dc.relation.uri | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/slct.202400178 | es_MX |
| dc.rights | openAccess - Acceso Abierto | es_MX |
| dc.subject | 2 - BIOLOGÍA Y QUÍMICA | es_MX |
| dc.subject.other | 23 - QUÍMICA | es_MX |
| dc.title | Synthesis of β-Truxinate via [2+2] Cycloaddition of Methyl 4-Nitrocinnamate: Kinetic Study of its Isomerization with DBU. | es_MX |
| dc.type | article - Artículo | es_MX |
| uaem.unidad | Facultad de Ciencias Químicas e Ingeniería - Facultad de Ciencias Químicas e Ingeniería | es_MX |
| uaem.unidad | Centro de Investigaciones Químicas (CIQ) - Instituto de Investigación en Ciencias Básicas y Aplicadas (IICBA) - Centro de Investigaciones Químicas (CIQ) - Instituto de Investigación en Ciencias Básicas y Aplicadas (IICBA) | es_MX |
| dc.type.publication | publishedVersion | es_MX |
| dc.audience | researchers - Investigadores | es_MX |
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